One finds, in Maxwell's writings on thermodynamics and statistical physics, a conception of the nature of these subjects that differs in interesting ways from the way that they are usually conceived. In particular, though—in agreement with the currently accepted view—Maxwell maintains that the second law of thermodynamics, as originally conceived, cannot be strictly true, the replacement he proposes is different from the version accepted by most physicists today. The modification of the second law accepted by most physicists is a probabilistic (...) one: although statistical fluctuations will result in occasional spontaneous differences in temperature or pressure, there is no way to predictably and reliably harness these to produce large violations of the original version of the second law. Maxwell advocates a version of the second law that is strictly weaker; the validity of even this probabilistic version is of limited scope, limited to situations in which we are dealing with large numbers of molecules en masse and have no ability to manipulate individual molecules. Connected with this is his concept of the thermodynamic concepts of heat, work, and entropy; on the Maxwellian view, these are concepts that must be relativized to the means we have available for gathering information about and manipulating physical systems. The Maxwellian view is one that deserves serious consideration in discussions of the foundation of statistical mechanics. It has relevance for the project of recovering thermodynamics from statistical mechanics because, in such a project, it matters which version of the second law we are trying to recover. (shrink)

This book provides an account of the nature of time, especially time's arrow and the role of entropy, at a semi-popular level. Special attention is given to statistical mechanics, the past hypothesis, and possible cosmological explanations thereof.

Historical records show that there was no real concept of probability in Europe before the mid-seventeenth century, although the use of dice and other randomizing objects was commonplace. Ian Hacking presents a philosophical critique of early ideas about probability, induction, and statistical inference and the growth of this new family of ideas in the fifteenth, sixteenth, and seventeenth centuries. Hacking invokes a wide intellectual framework involving the growth of science, economics, and the theology of the period. He argues that the (...) transformations that made it possible for probability concepts to emerge have constrained all subsequent development of probability theory and determine the space within which philosophical debate on the subject is still conducted. First published in 1975, this edition includes an introduction that contextualizes his book in light of developing philosophical trends. Ian Hacking is the winner of the Holberg International Memorial Prize 2009. (shrink)

It is generally thought that objective chances for particular events different from 1 and 0 and determinism are incompatible. However, there are important scientific theories whose laws are deterministic but which also assign non-trivial probabilities to events. The most important of these is statistical mechanics whose probabilities are essential to the explanations of thermodynamic phenomena. These probabilities are often construed as 'ignorance' probabilities representing our lack of knowledge concerning the microstate. I argue that this construal is incompatible with the role (...) of probability in explanation and laws. This is the 'paradox of deterministic probabilities'. After surveying the usual list of accounts of objective chance and finding them inadequate I argue that an account of chance sketched by David Lewis can be modified to solve the paradox of deterministic probabilities and provide an adequate account of the probabilities in deterministic theories like statistical mechanics. (shrink)

This is the sequel to my “Fifteen Arguments Against Finite Frequentism” ( Erkenntnis 1997), the second half of a long paper that attacks the two main forms of frequentism about probability. Hypothetical frequentism asserts: The probability of an attribute A in a reference class B is p iff the limit of the relative frequency of A ’s among the B ’s would be p if there were an infinite sequence of B ’s. I offer fifteen arguments against this analysis. I (...) consider various frequentist responses, which I argue ultimately fail. I end with a positive proposal of my own, ‘hyper-hypothetical frequentism’, which I argue avoids several of the problems with hypothetical frequentism. It identifies probability with relative frequency in a hyperfinite sequence of trials. However, I argue that this account also fails, and that the prospects for frequentism are dim. (shrink)

Information theory and statistical mechanics II.

Many results of modern physics—those of quantum mechanics, for instance—come in a probabilistic guise. But what do probabilistic statements in physics mean? Are probabilities matters of objective fact and part of the furniture of the world, as objectivists think? Or do they only express ignorance or belief, as Bayesians suggest? And how are probabilistic hypotheses justified and supported by empirical evidence? Finally, what does the probabilistic nature of physics imply for our understanding of the world? This volume is the first (...) to provide a philosophical appraisal of probabilities in all of physics. Its main aim is to make sense of probabilistic statements as they occur in the various physical theories and models and to provide a plausible epistemology and metaphysics of probabilities. The essays collected here consider statistical physics, probabilistic modelling, and quantum mechanics, and critically assess the merits and disadvantages of objectivist and subjectivist views of probabilities in these fields. In particular, the Bayesian and Humean views of probabilities and the varieties of Boltzmann's typicality approach are examined. The contributions on quantum mechanics discuss the special character of quantum correlations, the justification of the famous Born Rule, and the role of probabilities in a quantum field theoretic framework. Finally, the connections between probabilities and foundational issues in physics are explored. The Reversibility Paradox, the notion of entropy, and the ontology of quantum mechanics are discussed. Other essays consider Humean supervenience and the question whether the physical world is deterministic. (shrink)

This paper addresses the question of how we should regard the probability distributions introduced into statistical mechanics. It will be argued that it is problematic to take them either as purely ontic, or purely epistemic. I will propose a third alternative: they are almost objective probabilities, or epistemic chances. The definition of such probabilities involves an interweaving of epistemic and physical considerations, and thus they cannot be classified as either purely epistemic or purely ontic. This conception, it will be argued, (...) resolves some of the puzzles associated with statistical mechanical probabilities: it explains how probabilistic posits introduced on the basis of incomplete knowledge can yield testable predictions, and it also bypasses the problem of disastrous retrodictions, that is, the fact the standard equilibrium measures yield high probability of the system being in equilibrium in the recent past, even when we know otherwise. As the problem does not arise on the conception of probabilities considered here, there is no need to invoke a Past Hypothesis as a special posit to avoid it. (shrink)

The mathematical theory of communication.

This paper offers a metaphysics of physical probability in (or if you prefer, truth conditions for probabilistic claims about) deterministic systems based on an approach to the explanation of probabilistic patterns in deterministic systems called the method of arbitrary functions. Much of the appeal of the method is its promise to provide an account of physical probability on which probability assignments have the ability to support counterfactuals about frequencies. It is argued that the eponymous arbitrary functions are of little philosophical (...) use, but that they can be substituted for facts about frequencies without losing the ability to provide counterfactual support. The result is an account of probability in deterministic systems that has a “propensity-like” look and feel, yet which requires no supplement to the standard modern empiricist tool kit of particular matters of fact and principles of physical dynamics. (shrink)

Objective interpretations of probability are usually discussed in two varieties: frequency and propensity accounts. But there is a third, neglected possibility, namely, probabilities as deriving from ranges in suitably structured initial state spaces. Roughly, the probability of an event is the proportion of initial states that lead to this event in the space of all possible initial states, provided that this proportion is approximately the same in any not too small interval of the initial state space. This idea can also (...) be expressed by saying that in the types of situations that give rise to probabilistic phenomena we may expect to find an initial state space such that any "reasonable" density function over this space leads to the same probabilities for the possible outcomes. This "method of arbitrary functions" was introduced by Poincaré, studied and extended by Hopf and more recently by Eduardo Engel, Jan von Plato and Michael Strevens. The natural-range, or method-of-arbitrary-functions approach to probabilities is usually treated as an explanation for the occurrence of probabilistic patterns, whereas I examine its prospects for an objective interpretation of probability, in the sense of providing truth conditions for probability statements that do not depend on our state of mind or information. The main objection to such a proposal is that it is circular, i.e. presupposes the concept of probability, because a measure on the initial state has to be introduced, and density functions over the space are considered. I try to argue that this objection can be successfully met. (shrink)

Various processes are often classified as both deterministic and random or chaotic. The main difficulty in analysing the randomness of such processes is the apparent tension between the notions of randomness and determinism: what type of randomness could exist in a deterministic process? Ergodic theory seems to offer a particularly promising theoretical tool for tackling this problem by positing a hierarchy, the so-called ‘ergodic hierarchy’, which is commonly assumed to provide a hierarchy of increasing degrees of randomness. However, that notion (...) of randomness requires clarification. The mathematical definition of EH does not make explicit appeal to randomness; nor does the usual way of presenting EH involve a specification of the notion of randomness that is supposed to underlie the hierarchy. In this paper we argue that EH is best understood as a hierarchy of random behaviour if randomness is explicated in terms of unpredictability. We then show that, contrary to common wisdom, EH is useful in characterising the behaviour of Hamiltonian dynamical systems. (shrink)

In the last quarter of the nineteenth century, Ludwig Boltzmann explained how irreversible macroscopic laws, in particular the second law of thermodynamics, originate in the time-reversible laws of microscopic physics. Boltzmann’s analysis, the essence of which I shall review here, is basically correct. The most famous criticisms of Boltzmann’s later work on the subject have little merit. Most twentieth century innovations – such as the identification of the state of a physical system with a probability distribution on its phase space, (...) of its thermodynamic entropy with the Gibbs entropy of , and the invocation of the notions of ergodicity and mixing for the justification of the foundations of statistical mechanics – are thoroughly misguided. (shrink)

It is argued that certain recent advances in the construction of a theory of the collapses of Quantum Mechanical wave functions suggest the possibility of new and improved foundations for statistical mechanics, foundations in which epistemic considerations play no role.

This work has been selected by scholars as being culturally important, and is part of the knowledge base of civilization as we know it. This work was reproduced from the original artifact, and remains as true to the original work as possible. Therefore, you will see the original copyright references, library stamps, and other notations in the work. This work is in the public domain in the United States of America, and possibly other nations. Within the United States, you may (...) freely copy and distribute this work, as no entity has a copyright on the body of the work. As a reproduction of a historical artifact, this work may contain missing or blurred pages, poor pictures, errant marks, etc. Scholars believe, and we concur, that this work is important enough to be preserved, reproduced, and made generally available to the public. We appreciate your support of the preservation process, and thank you for being an important part of keeping this knowledge alive and relevant. (shrink)

Quantum mechanics, with its revolutionary implications, has posed innumerable problems to philosophers of science. In particular, it has suggested reconsidering basic concepts such as the existence of a world that is, at least to some extent, independent of the observer, the possibility of getting reliable and objective knowledge about it, and the possibility of taking (under appropriate circumstances) certain properties to be objectively possessed by physical systems. It has also raised many others questions which are well known to those involved (...) in the debate on the interpretation of this pillar of modern science. One can argue that most of the problems are not only due to the intrinsic revolutionary nature of the phenomena which have led to the development of the theory. They are also related to the fact that, in its standard formulation and interpretation, quantum mechanics is a theory which is excellent (in fact it has met with a success unprecedented in the history of science) in telling us everything about what we observe, but it meets with serious difficulties in telling us what is. We are making here specific reference to the central problem of the theory, usually referred to as the measurement problem, or, with a more appropriate term, as the macro-objectification problem. It is just one of the many attempts to overcome the difficulties posed by this problem that has led to the development of Collapse Theories, i.e., to the Dynamical Reduction Program (DRP). As we shall see, this approach consists in accepting that the dynamical equation of the standard theory should be modified by the addition of stochastic and nonlinear terms. The nice fact is that the resulting theory is capable, on the basis of a unique dynamics which is assumed to govern all natural processes, to account at the same time for all well-established.. (shrink)

An important contribution to the foundations of probability theory, statistics and statistical physics has been made by E. T. Jaynes. The recent publication of his collected works provides an appropriate opportunity to attempt an assessment of this contribution.

A proposal for an objective interpretation of probability is introduced and discussed: probabilities as deriving from ranges in suitably structured initial-state spaces. Roughly, the probability of an event on a chance trial is the proportion of initial states that lead to the event in question within the space of all possible initial states associated with this type of experiment, provided that the proportion is approximately the same in any not too small subregion of the space. This I would like to (...) call the “natural-range conception” of probability. Providing a substantial alternative to frequency or propensity accounts of probability in a deterministic setting, it is closely related to the so-called “method of arbitrary functions”. It is explicated, confronted with certain problems, and some ideas how these might be overcome are sketched and discussed. (shrink)

According to finite frequentism, the probability of an attribute A in a finite reference class B is the relative frequency of actual occurrences of A within B. I present fifteen arguments against this position.

We propose an "explanation scheme" for why the Gibbs phase average technique in classical equilibrium statistical mechanics works. Our account emphasizes the importance of the Khinchin-Lanford dispersion theorems. We suggest that ergodicity does play a role, but not the one usually assigned to it.

Statistical mechanics is one of the crucial fundamental theories of physics, and in his new book Lawrence Sklar, one of the pre-eminent philosophers of physics, offers a comprehensive, non-technical introduction to that theory and to attempts to understand its foundational elements. Among the topics treated in detail are: probability and statistical explanation, the basic issues in both equilibrium and non-equilibrium statistical mechanics, the role of cosmology, the reduction of thermodynamics to statistical mechanics, and the alleged foundation of the very notion (...) of time asymmetry in the entropic asymmetry of systems in time. The book emphasises the interaction of scientific and philosophical modes of reasoning, and in this way will interest all philosophers of science as well as those in physics and chemistry concerned with philosophical questions. The book could also be read by an informed general reader interested in the foundations of modern science. (shrink)

I describe a realist, ontologically objective interpretation of probability, "far-flung frequency (FFF) mechanistic probability". FFF mechanistic probability is defined in terms of facts about the causal structure of devices and certain sets of frequencies in the actual world. Though defined partly in terms of frequencies, FFF mechanistic probability avoids many drawbacks of well-known frequency theories and helps causally explain stable frequencies, which will usually be close to the values of mechanistic probabilities. I also argue that it's a virtue rather than (...) a failing of FFF mechanistic probability that it does not define single-case chances, and compare some aspects of my interpretation to a recent interpretation proposed by Strevens. (shrink)

In this paper, a concept of chance is introduced that is compatible with deterministic physical laws, yet does justice to our use of chance-talk in connection with typical games of chance. We take our cue from what Poincaré called "the method of arbitrary functions," and elaborate upon a suggestion made by Savage in connection with this. Comparison is made between this notion of chance, and David Lewis' conception.