Suppose that God or a demon informs you of the following future fact: despite recent cosmological evidence, the universe is indeed closed and it will have a ‘final’ instant of time; moreover, at that final moment, all 49 of the world’s Imperial Faberge eggs will be in your bedroom bureau’s sock drawer. You’re absolutely certain that this information is true. All of your other dealings with supernatural powers have demonstrated that they are a trustworthy lot.

Does not the theory of a general tendency of entropy to diminish [sic] take too much for granted? To a certain extent it is supported by experimental evidence. We must accept such evidence as far as it goes and no further. We have no right to supplement it by a large draft of the scientific imagination.

Roughly speaking, classical statistical physics is the branch of theoretical physics that aims to account for the thermal behaviour of macroscopic bodies in terms of a classical mechanical model of their microscopic constituents, with the help of probabilistic assumptions. In the last century and a half, a fair number of approaches have been developed to meet this aim. This study of their foundations assesses their coherence and analyzes the motivations for their basic assumptions, and the interpretations of their central concepts. (...) The most outstanding foundational problems are the explanation of time-asymmetry in thermal behaviour, the relative autonomy of thermal phenomena from their microscopic underpinning, and the meaning of probability. A more or less historic survey is given of the work of Maxwell, Boltzmann and Gibbs in statistical physics, and the problems and objections to which their work gave rise. Next, we review some modern approaches to (i) equilibrium statistical mechanics, such as ergodic theory and the theory of the thermodynamic limit; and to (ii) non-equilibrium statistical mechanics as provided by Lanford's work on the Boltzmann equation, the so-called Bogolyubov-Born-Green-Kirkwood-Yvon approach, and stochastic approaches such as `coarse-graining' and the `open systems' approach. In all cases, we focus on the subtle interplay between probabilistic assumptions, dynamical assumptions, initial conditions and other ingredients used in these approaches. (shrink)

A transcript of three lectures, given at Princeton University in 1970, which deals with (inter alia) debates concerning proper names in the philosophy of language.

This book is an attempt to get to the bottom of an acute and perennial tension between our best scientific pictures of the fundamental physical structure of the world and our everyday empirical experience of it. The trouble is about the direction of time. The situation (very briefly) is that it is a consequence of almost every one of those fundamental scientific pictures--and that it is at the same time radically at odds with our common sense--that whatever can happen can (...) just as naturally happen backwards. Albert provides an unprecedentedly clear, lively, and systematic new account--in the context of a Newtonian-Mechanical picture of the world--of the ultimate origins of the statistical regularities we see around us, of the temporal irreversibility of the Second Law of Thermodynamics, of the asymmetries in our epistemic access to the past and the future, and of our conviction that by acting now we can affect the future but not the past. Then, in the final section of the book, he generalizes the Newtonian picture to the quantum-mechanical case and (most interestingly) suggests a very deep potential connection between the problem of the direction of time and the quantum-mechanical measurement problem. The book aims to be both an original contribution to the present scientific and philosophical understanding of these matters at the most advanced level, and something in the nature of an elementary textbook on the subject accessible to interested high-school students. Table of Contents: Preface 1. Time-Reversal Invariance 2. Thermodynamics 3. Statistical Mechanics 4. The Reversibility Objections and the Past-Hypothesis 5. The Scope of Thermodynamics 6. The Asymmetries of Knowledge and Intervention 7. Quantum Mechanics Appendix: Gedankenexperiments with Heat Engines Index Reviews of this book: The foundations of statistical mechanisms are often presented in physics textbooks in a rather obscure and confused way. By challenging common ways of thinking about this subject, Time and Chance can do quite a lot to improve this situation. --Jean Bricmont, Science Albert is perfecting a style of foundational analysis that is uniquely his own...It has a surgical precision...and it is ruthless with pretensions. The foundations of thermodynamics is a topic that has accumulated a good deal of dead wood; this is a fire that will burn and burn. --Simon W. Saunders, Oxford University As usual with Albert's work, the exposition is brisk and to the point, and exceptionally clear...The book will be an extremely valuable contribution to the literature on the subject of philosophical issues in thermodynamics and statistical mechanics, a literature which has been thin on the ground but is now growing as it deserves to. --Lawrence Sklar, University of Michigan. (shrink)

This book provides an account of the nature of time, especially time's arrow and the role of entropy, at a semi-popular level. Special attention is given to statistical mechanics, the past hypothesis, and possible cosmological explanations thereof.

We reconsider the Nagelian theory of reduction and argue that, contrary to a widely held view, it is the right analysis of intertheoretic reduction. The alleged difficulties of the theory either vanish upon closer inspection or turn out to be substantive philosophical questions rather than knock-down arguments.

The law of gravitation, an example of physical law The relation of mathematics to physics The great conservation principles Symmetry in physical law The distinction of past and future Probability and uncertainty: the quantum mechanical view of nature Seeking new laws.

In his bestselling work of popular science, Sir Roger Penrose takes us on a fascinating roller-coaster ride through the basic principles of physics, cosmology, mathematics, and philosophy to show that human thinking can never be emulated by a machine.

Why is the future so different from the past? Why does the past affect the future and not the other way round? The universe began with the Big Bang - will it end with a `Big Crunch'? Now in paperback, this book presents an innovative and controversial view of time and contemporary physics. Price urges physicists, philosophers, and anyone who has ever pondered the paradoxes of time to look at the world from a fresh perspective, and throws fascinating new light (...) on some of the great mysteries of the universe. (shrink)

Gases reach equilibrium when left to themselves. Why do they behave in this way? The canonical answer to this question, originally proffered by Boltzmann, is that the systems have to be ergodic. This answer has been criticised on different grounds and is now widely regarded as flawed. In this paper we argue that some of the main arguments against Boltzmann's answer, in particular, arguments based on the KAM-theorem and the Markus-Meyer theorem, are beside the point. We then argue that something (...) close to Boltzmann's original proposal is true for gases: gases behave thermodynamic-like if they are epsilon-ergodic, i.e., ergodic on the entire accessible phase space except for a small region of measure epsilon. This answer is promising because there are good reasons to believe that relevant systems in statistical mechanics are epsilon-ergodic. (shrink)

_Naming and Necessity_ has had a great and increasing influence. It redirected philosophical attention to neglected questions of natural and metaphysical necessity and to the connections between these and theories of naming, and of identity. This seminal work, to which today's thriving essentialist metaphysics largely owes its impetus, is here reissued in a newly corrected form with a new preface by the author. If there is such a thing as essential reading in metaphysics, or in philosophy of language, this is (...) it. (shrink)

Winner of the Wolf Prize for his contribution to our understanding of the universe, Penrose takes on the question of whether artificial intelligence will ever ...

In the last quarter of the nineteenth century, Ludwig Boltzmann explained how irreversible macroscopic laws, in particular the second law of thermodynamics, originate in the time-reversible laws of microscopic physics. Boltzmann’s analysis, the essence of which I shall review here, is basically correct. The most famous criticisms of Boltzmann’s later work on the subject have little merit. Most twentieth century innovations – such as the identification of the state of a physical system with a probability distribution on its phase space, (...) of its thermodynamic entropy with the Gibbs entropy of , and the invocation of the notions of ergodicity and mixing for the justification of the foundations of statistical mechanics – are thoroughly misguided. (shrink)

Bohmian mechanics is a theory about point particles moving along trajectories. It has the property that in a world governed by Bohmian mechanics, observers see the same statistics for experimental results as predicted by quantum mechanics. Bohmian mechanics thus provides an explanation of quantum mechanics. Moreover, the Bohmian trajectories are defined in a non-conspiratorial way by a few simple laws.

Some philosphers of science of an empiricist and pragmatist bent have proposed models of statistical explanation, but have then become sceptical of the adequacy of these models. It is argued that general considerations concerning the purpose of function of explanation in science which are usually appealed to by such philosophers show that their scepticism is not well taken; for such considerations provide much the same rationale for the search for statistical explanations, as these philosophers have characterized them, as they do (...) for lawlike explanations. But, it is further argued, a significant piece of what is frequently offered as an explanation of well known phenomena in statistical mechanics, fails to meet this general "pragmatic rationale" for statistical, or indeed any kind of, explanation. The question then arises whether the physicists have misconstrued the value of this piece of physical theorizing, ergodic theory, taking it to be explanatory when it is actually not; or whether, instead, the philosopher's account of just what is genuinely explanatory is too narrow. (shrink)

The year 2005 has been named the World Year of Physics in recognition of the 100th anniversary of Albert Einstein's "Miracle Year," in which he published four landmark papers which had deep and great influence on the last and the current century: quantum theory, general relativity, and statistical mechanics. Despite the enormous importance that Einstein’s discoveries played in these theories, most physicists adopt a version of quantum theory which is incompatible with the idea that motivated Einstein in the first place. (...) This seems to suggest that Einstein was fundamentally incapable of appreciating the `quantum revolution,’ and that his vision of physics as an attempt to reach a complete and comprehensive description of reality was ultimately impossible to obtain. Relativity theory has provided us with a picture of reality in which the world can be though as independent on who observes it, and the same can be said for statistical mechanics. Instead, quantum mechanics seems to suggest that physical objects do not exist `out there’ when someone is not observing them. In this framework, it is often suggested that any kind of causal explanation is impossible in the atomic and subatomic world, and therefore should be abandoned. This is why many think that it is in principle impossible for quantum theory to provide us with a coherent and comprehensive view of the world, in contrast with what happens with relativity and statistical mechanics. Is it really impossible to pursue Einstein’s ideal of physics also in the quantum framework? This book argues that this is not the case: the central idea is that Einstein’s vision of physics is still a live option, and indeed it is the one that best allows obtaining a unitary understanding of our physical theories. One can consider all the three theories mentioned above, suitably modified, as theories that are able to account and explain the world around us without too much departure from the classical framework. ---------------------------------------------------------------------------------------------------- -------------------------------------------------- -/- La teoria della relatività, la meccanica statistica e la meccanica quantistica hanno profondamente rivoluzionato il nostro modo di concepire spazio, tempo, materia, probabilità e causalità, nonché il rapporto tra universo fisico ed osservatore, nozioni che sono state al centro della discussione filosofica dal mondo greco fino ai nostri giorni. Questo volume, opera di Valia Allori, Mauro Dorato, Federico Laudisa e Nino Zanghì, non solo intende suggerire nuovi metodi di confronto tra fisica e filosofia, ma prova altresì a rendere espliciti i presupposti filosofici che sono presenti nell'interpretazione che i fisici stessi danno del formalismo matematico. (shrink)

A gas prepared in a non-equilibrium state will approach equilibrium and stay there. An influential contemporary approach to Statistical Mechanics explains this behaviour in terms of typicality. However, this explanation has been criticised as mysterious as long as no connection with the dynamics of the system is established. We take this criticism as our point of departure. Our central claim is that Hamiltonians of gases which are epsilon-ergodic are typical with respect to the Whitney topology. Because equilibrium states are typical, (...) we argue that there follows the desired conclusion that typical initial conditions approach equilibrium and stay there. (shrink)

An important contemporary version of Boltzmannian statistical mechanics explains the approach to equilibrium in terms of typicality. The problem with this approach is that it comes in different versions, which are, however, not recognized as such and not clearly distinguished. This article identifies three different versions of typicality‐based explanations of thermodynamic‐like behavior and evaluates their respective successes. The conclusion is that the first two are unsuccessful because they fail to take the system's dynamics into account. The third, however, is promising. (...) I give a precise formulation of the proposal and present an argument in support of its central contention. †To contact the author, please write to: Department of Philosophy, Logic, and Scientific Method, London School of Economics, Houghton Street, London WC2A 2AE, England; e‐mail: [email protected]. (shrink)

Why do systems prepared in a non-equilibrium state approach, and eventually reach, equilibrium? An important contemporary version of the Boltzmannian approach to statistical mechanics answers this question by an appeal to the notion of typicality. The problem with this approach is that it comes in different versions, which are, however, not recognised as such, much less clearly distinguished, and we often find different arguments pursued side by side. The aim of this paper is to disentangle different versions of typicality-based explanations (...) of thermodynamic behaviour and evaluate their respective success. My conclusion will be that the boldest version fails for technical reasons, while more prudent versions leave unanswered essential questions. (shrink)

Why do systems prepared in a non-equilibrium state approach, and eventually reach, equilibrium? An important contemporary version of the Boltzmannian approach to statistical mechanics answers this question by an appeal to the notion of typicality. The problem with this approach is that it comes in different versions, which are, however, not recognised as such, much less clearly distinguished, and we often find different arguments pursued side by side. The aim of this paper is to disentangle different versions of typicality-based explanations (...) of thermodynamic behaviour and evaluate their respective success. My conclusion will be that the boldest version fails for technical reasons, while more prudent versions leave unanswered essential questions. (shrink)