Determinism is a perennial topic of philosophical discussion. Very little acquaintance with the philosophical literature is needed to reveal the Tower of ...

A rational person doesn’t believe just anything. There are limits on what it is rational to believe. How wide are these limits? That’s the main question that interests me here. But a secondary question immediately arises: What factors impose these limits? A first stab is to say that one’s evidence determines what it is epistemically permissible for one to believe. Many will claim that there are further, non-evidentiary factors relevant to the epistemic rationality of belief. I will be ignoring the (...) details of alternative answers in order to focus on the question of what kind of rational constraints one’s evidence puts on belief. Our main question concerns how far epistemic permission and obligation can come apart.1 Suppose I am epistemically permitted to believe P, i.e., it would not be irrational for me to believe it. Am I thereby obliged to believe P, or are other options rationally available to me?2 Might I be equally rational in remaining agnostic about P, or even believing not-P? Or could even a slightly stronger or weaker degree of confidence be just as reasonable? (shrink)

Statistical mechanics is one of the crucial fundamental theories of physics, and in his new book Lawrence Sklar, one of the pre-eminent philosophers of physics, offers a comprehensive, non-technical introduction to that theory and to attempts to understand its foundational elements. Among the topics treated in detail are: probability and statistical explanation, the basic issues in both equilibrium and non-equilibrium statistical mechanics, the role of cosmology, the reduction of thermodynamics to statistical mechanics, and the alleged foundation of the very notion (...) of time asymmetry in the entropic asymmetry of systems in time. The book emphasises the interaction of scientific and philosophical modes of reasoning, and in this way will interest all philosophers of science as well as those in physics and chemistry concerned with philosophical questions. The book could also be read by an informed general reader interested in the foundations of modern science. (shrink)

The Dappled World: A Study of the Boundaries of Science. nancy cartwright. Plato's Reception of Parmenides. john a. palmer.

It is generally thought that objective chances for particular events different from 1 and 0 and determinism are incompatible. However, there are important scientific theories whose laws are deterministic but which also assign non-trivial probabilities to events. The most important of these is statistical mechanics whose probabilities are essential to the explanations of thermodynamic phenomena. These probabilities are often construed as 'ignorance' probabilities representing our lack of knowledge concerning the microstate. I argue that this construal is incompatible with the role (...) of probability in explanation and laws. This is the 'paradox of deterministic probabilities'. After surveying the usual list of accounts of objective chance and finding them inadequate I argue that an account of chance sketched by David Lewis can be modified to solve the paradox of deterministic probabilities and provide an adequate account of the probabilities in deterministic theories like statistical mechanics. (shrink)

We are used to talking about the “structure” posited by a given theory of physics, such as the spacetime structure of relativity. What is “structure”? What does the mathematical structure used to formulate a theory tell us about the physical world according to the theory? What if there are different mathematical formulations of a given theory? Do different formulations posit different structures, or are they merely notational variants? I consider the case of Lagrangian and Hamiltonian classical mechanics. I argue that, (...) contrary to standard wisdom, these are not genuinely equivalent theories: they differ in statespace structure. I suggest that we should be realists about statespace structure. (shrink)

It has become something of a dogma in the philosophy of science that modern cosmology has completed Boltzmann's program for explaining the statistical validity of the Second Law of thermodynamics by providing the low entropy initial state needed to ground the asymmetry in entropic behavior that underwrites our inference about the past. This dogma is challenged on several grounds. In particular, it is argued that it is likely that the Boltzmann entropy of the initial state of the universe is an (...) ill-defined or severely hobbled concept. It is also argued that even if the entropy of the initial state of the universe had a well-defined, low value, this would not suffice to explain why thermodynamics works as well as it does for the kinds of systems we care about. Because the role of Boltzmann entropy in our inferences to the past has been vastly overrated, the failure of the Boltzmann program does not pose a serious problem for our knowledge of the past. But it does call a different explanation of why thermodynamics works as well as it does. A suggestion is offered for a different approach. (shrink)

This paper discusses the mistake of understanding the laws and concepts of thermodynamics too literally in the foundations of statistical mechanics. Arguing that this error is still made in subtle ways, the article explores its occurrence in three examples: the Second Law, the concept of equilibrium and the definition of phase transitions.

Newton’s equations of motion tell us that a mass at rest at the apex of a dome with the shape specified here can spontaneously move. It has been suggested that this indeterminism should be discounted since it draws on an incomplete rendering of Newtonian physics, or it is “unphysical,” or it employs illicit idealizations. I analyze and reject each of these reasons. †To contact the author, please write to: Department of History and Philosophy of Science, University of Pittsburgh, Pittsburgh, PA (...) 15260; e‐mail: [email protected]. (shrink)

This is an extensive review of recent work on the foundations of statistical mechanics.

Roughly speaking, classical statistical physics is the branch of theoretical physics that aims to account for the thermal behaviour of macroscopic bodies in terms of a classical mechanical model of their microscopic constituents, with the help of probabilistic assumptions. In the last century and a half, a fair number of approaches have been developed to meet this aim. This study of their foundations assesses their coherence and analyzes the motivations for their basic assumptions, and the interpretations of their central concepts. (...) The most outstanding foundational problems are the explanation of time-asymmetry in thermal behaviour, the relative autonomy of thermal phenomena from their microscopic underpinning, and the meaning of probability. A more or less historic survey is given of the work of Maxwell, Boltzmann and Gibbs in statistical physics, and the problems and objections to which their work gave rise. Next, we review some modern approaches to (i) equilibrium statistical mechanics, such as ergodic theory and the theory of the thermodynamic limit; and to (ii) non-equilibrium statistical mechanics as provided by Lanford's work on the Boltzmann equation, the so-called Bogolyubov-Born-Green-Kirkwood-Yvon approach, and stochastic approaches such as `coarse-graining' and the `open systems' approach. In all cases, we focus on the subtle interplay between probabilistic assumptions, dynamical assumptions, initial conditions and other ingredients used in these approaches. (shrink)

The most important theories in fundamental physics, quantum mechanics and statistical mechanics, posit objective probabilities or chances. As important as chance is there is little agreement about what it is. The usual “interpretations of probability” give very different accounts of chance and there is disagreement concerning which, if any, is capable of accounting for its role in physics. David Lewis has contributed enormously to improving this situation. In his classic paper “A Subjectivist's Guide to Objective Chance” he described a framework (...) for representing single case objective chances, showed how they are connected to subjective credences, and sketched a novel account what they are within his Humean account of scientific laws. Here I will describe these contributions and add a little to them. (shrink)

In the last quarter of the nineteenth century, Ludwig Boltzmann explained how irreversible macroscopic laws, in particular the second law of thermodynamics, originate in the time-reversible laws of microscopic physics. Boltzmann’s analysis, the essence of which I shall review here, is basically correct. The most famous criticisms of Boltzmann’s later work on the subject have little merit. Most twentieth century innovations – such as the identification of the state of a physical system with a probability distribution on its phase space, (...) of its thermodynamic entropy with the Gibbs entropy of , and the invocation of the notions of ergodicity and mixing for the justification of the foundations of statistical mechanics – are thoroughly misguided. (shrink)

This article argues that most of the approaches to the foundations of statistical mechanics have severed their link with the original foundational project, the project of demonstrating how real mechanical systems can behave thermodynamically.

Why does classical equilibrium statistical mechanics work? Malament and Zabell (1980) noticed that, for ergodic dynamical systems, the unique absolutely continuous invariant probability measure is the microcanonical. Earman and Rédei (1996) replied that systems of interest are very probably not ergodic, so that absolutely continuous invariant probability measures very distant from the microcanonical exist. In response I define the generalized properties of epsilon-ergodicity and epsilon-continuity, I review computational evidence indicating that systems of interest are epsilon-ergodic, I adapt Malament and Zabell’s (...) defense of absolute continuity to support epsilon-continuity, and I prove that, for epsilon-ergodic systems, every epsilon-continuous invariant probability measure is very close to the microcanonical. (shrink)

The role of probability is one of the most contested issues in the interpretation of contemporary physics. In this paper, I’ll be reevaluating some widely held assumptions about where and how probabilities arise. Larry Sklar voices the conventional wisdom about probability in classical physics in a piece in the Stanford Online Encyclopedia of Philosophy, when he writes that “Statistical mechanics was the first foundational physical theory in which probabilistic concepts and probabilistic explanation played a fundamental role.” And the conventional wisdom (...) about quantum probabilities is that they are basic, not reducible to the types of probabilities we see in statistical mechanics. In the first section of this paper, I’ll argue that in fact classical physics was steeped in probability long before statistical mechanics came on the scene, specifically, that an objective measure over phase space is an indispensable component of any informative physical theory. In the next section, I’ll argue that this objective measure is the fundamental form of physical probability and that quantum probabilities can be defined in terms of it. In the last, I’ll raise some questions about the metaphysical status of the fundamental measure. (shrink)

We argue that, contrary to some analyses in the philosophy of science literature, ergodic theory falls short in explaining the success of classical equilibrium statistical mechanics. Our claim is based on the observations that dynamical systems for which statistical mechanics works are most likely not ergodic, and that ergodicity is both too strong and too weak a condition for the required explanation: one needs only ergodic-like behaviour for the finite set of observables that matter, but the behaviour must ensure that (...) the approach to equilibrium for these observables is on the appropriate time-scale. (shrink)

For the generalizations of thermodynamics to obtain, it appears that a very ‘special’ initial condition of the universe is required. Is this initial condition itself in need of explanation? I argue that it is not. In so doing, I offer a framework in which to think about ‘special’ initial conditions in all areas of science, though I concentrate on the case of thermodynamics. I urge the view that it is not always a serious mark against a theory that it must (...) posit an ‘improbable’ initial condition. (shrink)

The epistemic state of complete ignorance is not a probability distribution. In it, we assign the same, unique, ignorance degree of belief to any contingent outcome and each of its contingent, disjunctive parts. That this is the appropriate way to represent complete ignorance is established by two instruments, each individually strong enough to identify this state. They are the principle of indifference (PI) and the notion that ignorance is invariant under certain redescriptions of the outcome space, here developed into the (...) ‘principle of invariance of ignorance' (PII). Both instruments are so innocuous as almost to be platitudes. Yet the literature in probabilistic epistemology has misdiagnosed them as paradoxical or defective since they generate inconsistencies when conjoined with the assumption that an epistemic state must be a probability distribution. To underscore the need to drop this assumption, I express PII in its most defensible form as relating symmetric descriptions and show that paradoxes still arise if we assume the ignorance state to be a probability distribution. *Received February 2007; revised July 2007. †To contact the author, please write to: Department of History and Philosophy of Science, University of Pittsburgh, Pittsburgh, PA 15260; e-mail: [email protected]. (shrink)

In his recent book, Time and Chance, David Albert claims that by positing that there is a uniform probability distribution defined, on the standard measure, over the space of microscopic states that are compatible with both the current macrocondition of the world, and with what he calls the “past hypothesis”, we can explain the time asymmetry of all of the thermodynamic behavior in the world. The principal purpose of this paper is to dispute this claim. I argue that Albert's proposal (...) fails in his stated goal—to show how to use the time‐reversible dynamics of Newtonian physics to “underwrite the actual content of our thermodynamic experience” (Albert 2000, 159). Albert's proposal can satisfactorily explain why the overall entropy of the universe as a whole is increasing, but it does not and cannot explain the increasing entropy of relatively small, relatively short‐lived systems in energetic isolation without making use of a principle that leads to reversibility objections. (shrink)

Philosophers of physics are very familiar with foundational problems in quantum mechanics and in the theory of relativity. In both fields, the puzzles, if not solved, are at least reasonably well formulated and possess well-characterized solution strategies. Sklar’s book Physics and Chance focuses on a pair of theories, thermodynamics and statistical mechanics, for which puzzles and foundational paradoxes abound, but where there is very little agreement upon the means with which they may best be approached. As he notes in the (...) introduction. (shrink)

The principle of indifference is supposed to suffice for the rational assignation of probabilities to possibilities. Bertrand advances a probability problem, now known as his paradox, to which the principle is supposed to apply; yet, just because the problem is ill‐posed in a technical sense, applying it leads to a contradiction. Examining an ambiguity in the notion of an ill‐posed problem shows that there are precisely two strategies for resolving the paradox: the distinction strategy and the well‐posing strategy. The main (...) contenders for resolving the paradox, Marinoff and Jaynes, offer solutions which exemplify these two strategies. I show that Marinoff’s attempt at the distinction strategy fails, and I offer a general refutation of this strategy. The situation for the well‐posing strategy is more complex. Careful formulation of the paradox within measure theory shows that one of Bertrand’s original three options can be ruled out but also shows that piecemeal attempts at the well‐posing strategy will not succeed. What is required is an appeal to general principle. I show that Jaynes’s use of such a principle, the symmetry requirement, fails to resolve the paradox; that a notion of metaindifference also fails; and that, while the well‐posing strategy may not be conclusively refutable, there is no reason to think that it can succeed. So the current situation is this. The failure of Marinoff’s and Jaynes’s solutions means that the paradox remains unresolved, and of the only two strategies for resolution, one is refuted and we have no reason to think the other will succeed. Consequently, Bertrand’s paradox continues to stand in refutation of the principle of indifference. (shrink)

Or better: time asymmetry in thermodynamics. Better still: time asymmetry in thermodynamic phenomena. “Time in thermodynamics” misleadingly suggests that thermodynamics will tell us about the fundamental nature of time. But we don’t think that thermodynamics is a fundamental theory. It is a theory of macroscopic behavior, often called a “phenomenological science.” And to the extent that physics can tell us about the fundamental features of the world, including such things as the nature of time, we generally think that only fundamental (...) physics can. On its own, a science like thermodynamics won’t be able to tell us about time per se. But the theory will have much to say about everyday processes that occur in time; and in particular, the apparent asymmetry of those processes. The pressing question of time in the context of thermodynamics is about the asymmetry of things in time, not the asymmetry of time, to paraphrase Price ( , ). I use the title anyway, to underscore what is, to my mind, the centrality of thermodynamics to any discussion of the nature of time and our experience in it. The two issues—the temporal features of processes in time, and the intrinsic structure of time itself—are related. Indeed, it is in part this relation that makes the question of time asymmetry in thermodynamics so interesting. This, plus the fact that thermodynamics describes a surprisingly wide range of our ordinary experience. We’ll return to this. First, we need to get the question of time asymmetry in thermodynamics out on the table. (shrink)

We propose an "explanation scheme" for why the Gibbs phase average technique in classical equilibrium statistical mechanics works. Our account emphasizes the importance of the Khinchin-Lanford dispersion theorems. We suggest that ergodicity does play a role, but not the one usually assigned to it.

Since the late nineteenth century, physics has been puzzled by the time-asymmetry of thermodynamic phenomena in the light of the apparent T-symmetry of the underlying laws of mechanics. However, a compelling solution to this puzzle has proved elusive. In part, I argue, this can be attributed to a failure to distinguish two conceptions of the problem. According to one, the main focus of our attention is a time-asymmetric lawlike generalisation. According to the other, it is a particular fact about the (...) early universe. This paper aims (i) to distinguish these two different conceptions of the time-asymmetric explanandum in thermodynamics; (ii) to argue in favour of the latter; and (iii) to show that whichever we choose, our rational expectations about the thermodynamic behaviour of the future must depend on what we know about the past: contrary to the common view, statistical arguments alone do not give us good reason to expect that entropy will always continue to increase. (shrink)

Statistical mechanics involves probabilities. At the same time, most approaches to the foundations of statistical mechanics--programs whose goal is to understand the macroscopic laws of thermal physics from the point of view of microphysics--are classical; they begin with the assumption that the underlying dynamical laws that govern the microscopic furniture of the world are deterministic. This raises some potential puzzles about the proper interpretation of these probabilities.

This paper justifies the inference of probabilities from symmetries. I supply some examples of important and correct inferences of this variety. Two explanations of such inferences -- an explanation based on the Principle of Indifference and a proposal due to Poincaré and Reichenbach -- are considered and rejected. I conclude with my own account, in which the inferences in question are shown to be warranted a posteriori, provided that they are based on symmetries in the mechanisms of chance setups.

Some philosphers of science of an empiricist and pragmatist bent have proposed models of statistical explanation, but have then become sceptical of the adequacy of these models. It is argued that general considerations concerning the purpose of function of explanation in science which are usually appealed to by such philosophers show that their scepticism is not well taken; for such considerations provide much the same rationale for the search for statistical explanations, as these philosophers have characterized them, as they do (...) for lawlike explanations. But, it is further argued, a significant piece of what is frequently offered as an explanation of well known phenomena in statistical mechanics, fails to meet this general "pragmatic rationale" for statistical, or indeed any kind of, explanation. The question then arises whether the physicists have misconstrued the value of this piece of physical theorizing, ergodic theory, taking it to be explanatory when it is actually not; or whether, instead, the philosopher's account of just what is genuinely explanatory is too narrow. (shrink)

This chapter unfolds a central philosophical problem of statistical mechanics. This problem lies in a clash between the Static Probabilities offered by statistical mechanics and the Dynamic Probabilities provided by classical or quantum mechanics. The chapter looks at the Boltzmann and Gibbs approaches in statistical mechanics and construes some of the great controversies in the field — for instance the Reversibility Paradox — as instances of this conflict. It furthermore argues that a response to this conflict is a critical choice (...) that shapes one's understanding of statistical mechanics itself, namely, whether it is to be conceived as a special or fundamental science. The chapter details some of the pitfalls of the latter ‘globalist’ position and seeks defensible ground for a kind of ‘localist’ alternative. (shrink)

In my contribution to the Symposium ("On the Vagaries of Determinism and Indeterminism"), I will identify several issues that arise in trying to decide whether Newtonian particle mechanics qualifies as a deterministic theory. I'll also give a mini-tutorial on the geometry and dynamical properties of Norton's dome surface. The goal is to better understand how his example works, and better appreciate just how wonderfully strange it is.

An investigation is made into how the foundations of statistical mechanics are affected once we treat classical mechanics as an approximation to quantum mechanics in certain domains rather than as a theory in its own right; this is necessary if we are to understand statistical-mechanical systems in our own world. Relevant structural and dynamical differences are identified between classical and quantum mechanics (partly through analysis of technical work on quantum chaos by other authors). These imply that quantum mechanics significantly affects (...) a number of foundational questions, including the nature of statistical probability and the direction of time. (shrink)

This paper is a discussion of David Albert's approach to the foundations of classical statistical menchanics. I point out a respect in which his account makes a stronger claim about the statistical mechanical probabilities than is usually made, and I suggest what might be motivation for this. I outline a less radical approach, which I attribute to Boltzmann, and I give some reasons for thinking that this approach is all we need, and also the most we are likely to get. (...) The issue between the two accounts turns out to be one about the explanatory role probabilities play in statistical mechanics. (shrink)

The Past Hypothesis is the claim that the Boltzmann entropy of the universe was extremely low when the universe began. Can we make sense of this claim when *classical* gravitation is included in the system? I first show that the standard rationale for not worrying about gravity is too quick. If the paper does nothing else, my hope is that it gets the problems induced by gravity the attention they deserve in the foundations of physics. I then try to make (...) plausible a very weak claim: that there is a well-defined Boltzmann entropy that *can* increase in *some* interesting self-gravitating systems. More work is needed before we can say whether this claim answers the threat to the standard explanation of entropy increase. (shrink)

The traditional use of ergodic theory in the foundations of equilibrium statistical mechanics is that it provides a link between thermodynamic observables and microcanonical probabilities. First of all, the ergodic theorem demonstrates the equality of microcanonical phase averages and infinite time averages (albeit for a special class of systems, and up to a measure zero set of exceptions). Secondly, one argues that actual measurements of thermodynamic quantities yield time averaged quantities, since measurements take a long time. The combination of these (...) two points is held to be an explanation why calculating microcanonical phase averages is a successful algorithm for predicting the values of thermodynamic observables. It is also well-known that this account is problematic.

This survey intends to show that ergodic theory nevertheless may have important roles to play, and it explores three other uses of ergodic theory. Particular attention is paid, firstly, to the relevance of specific interpretations of probability, and secondly, to the way in which the concern with systems in thermal equilibrium is translated into probabilistic language. With respect to the latter point, it is argued that equilibrium should not be represented as a stationary probability distribution as is standardly done; instead, a weaker definition is presented. (shrink)

This paper considers the possibility that nonrelativistic quantum mechanics tells us that Nature cares about time reversal. In a classical world we have a fundamentally reversible world that appears irreversible at higher levels, e.g., the thermodynamic level. But in a quantum world we see, if I am correct, a fundamentally irreversible world that appears reversible at higher levels, e.g., the level of classical mechanics. I consider two related symmetries, time reversal invariance and what I call ‘Wigner reversal invariance.’ Violation of (...) the first is interesting, for not only would it fly in the face of the usual story about temporal symmetry, but it also appears to imply (as I’ll explain) that time is ‘handed’, or as some have misleadingly said in the literature, ‘anisotropic’. Violation of the second is, as I hope to show, even more interesting. The paper also contains a discussion of two mostly neglected topics: what it means to say time is handed and what warrants such an attribution to time. (shrink)